4805-23-6Relevant academic research and scientific papers
A Bithiophene-Promoted ppm Levels of Palladium-Catalyzed Regioselective Hydrosilylation of Terminal Allenes
Chen, Jun-Jia,Zeng, Jia-Hao,Yang, Ying,Liu, Zhi-Kai,Jiang, Ya-Nan,Li, Miao-Ran,Chen, Li,Zhan, Zhuang-Ping
, p. 2360 - 2366 (2020)
A bithiophene?alkyne-based compound was synthesized and first utilized as a ligand for the selective hydrosilylation of allenes with primary and secondary phenylsilanes. It shows high selectivity towards the production of branched allylsilanes with a wide range of allenes. It is worth mentioning that the catalytic loading of the palladium can be reduced to 500 ppm. This work opens a new front of using bidentate thiophene ligand as a reaction promoter in transition-metal-catalyzed organic reaction. (Figure presented.).
