48121-05-7Relevant academic research and scientific papers
Epoxy compound using thiol-ene reaction and method for preparing the same, and composite of organic-inorganic materials comprising a cured product thereof and method for preparing the composite
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Paragraph 0133; 0134; 0136; 0137, (2018/08/28)
The present invention relates to: an epoxy compound having an alkoxysilyl alkyl-S-alkyl group; a manufacturing method thereof; an organic-inorganic material composite including a cured product thereof; and a method for manufacturing the composite, and mor
Epoxy compound using thiol-ene reaction and method for preparing the same, and composite of organic-inorganic materials comprising a cured product thereof and method for preparing the composite
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Paragraph 0133-0137, (2017/08/02)
The present invention relates to an epoxy compound having an alkoxysilylalkyl-S-alkyl group and a method for preparing the same, and a composite of organic-inorganic materials comprising a cured product thereof and a method for preparing the composite. Th
COLORED CHARGED SILSESQUIOXANES
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Paragraph 0830; 0832; 0836-0837, (2018/02/10)
The present invention provides compounds of Formula (1A), wherein Formula (II) is Formula (III) and Formula (1B) wherein Formula (IV) is Formula (V) and electrophoretic devices comprising the compounds of formula (1A) or (1B).
Designer ligands. Part 12.1 Synthesis and evaluation of novel palladium(II)-selective ligand systems
Gxoyiya, Babalwa S.B.,Hagemann, Justin P.,Kaye, Perry T.
, p. 252 - 256 (2007/10/03)
Sulfur-containing, PGM-selective, diamide ligands, developed for solvent extraction applications or use in the construction of molecularly imprinted polymers (MIPs), have been shown to exhibit significant selectivity for palladium(II) over copper(II), nickel(II) and cobalt(II).
Ruthenium-Catalyzed Chemoselective N-Allyl Cleavage: Novel Grubbs Carbene Mediated Deprotection of Allylic Amines
Alcaide, Benito,Almendros, Pedro,Alonso, Jose M.
, p. 5793 - 5799 (2007/10/03)
A novel application of the Grubbs carbene complex has been discovered. The first examples of the catalytic deprotection of allylic amines with reagents other than palladium catalysts have been achieved through Grubbs carbene mediated reaction. Significantly, the catalytic system directs the reaction toward the selective deprotection of allylic amines (secondary as well as tertiary) in the presence of allylic ethers. A variety of substrates, including enantiomerically pure multifunctional piperidines, are also usable. The new method is more convenient, chemoselective, and operationally simple than the palladium-catalyzed method. The current mechanistic hypothesis invokes a nitrogen-assisted ruthenium-catalyzed isomerization, followed by hydrolysis of the enamine intermediate. We believe that the reactive species involved in the reaction may be an Ru-H species rather than the Grubbs carbene itself. Thus, the isomerization may occur according to the hydride mechanism. The synthetic utility of this ruthenium-catalyzed allyl cleavage is illustrated by the preparation of indolizidine-type alkaloids.
