Welcome to LookChem.com Sign In|Join Free

CAS

  • or

48145-04-6

Post Buying Request

48145-04-6 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

48145-04-6 Usage

Uses

Different sources of media describe the Uses of 48145-04-6 differently. You can refer to the following data:
1. 2-Phenoxyethyl Acrylate is used as a monomer in multifunctional and shape memory polymers.
2. Ethylene glycol phenyl ether acrylate (PA) monomer may be used to fabricate polymerization induced grating pattern on photopolymer films.

General Description

Ethylene glycol phenyl ether acrylate (PA) is a monofunctional acrylate.

Flammability and Explosibility

Nonflammable

Safety Profile

Moderately toxic by skin contact. Mdly toxic by ingestion. A skin irritant. A combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes

Check Digit Verification of cas no

The CAS Registry Mumber 48145-04-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 4,8,1,4 and 5 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 48145-04:
(7*4)+(6*8)+(5*1)+(4*4)+(3*5)+(2*0)+(1*4)=116
116 % 10 = 6
So 48145-04-6 is a valid CAS Registry Number.
InChI:InChI=1/C11H12O3/c1-3-11(12)14-9(2)13-10-7-5-4-6-8-10/h3-9H,1H2,2H3

48145-04-6 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (L12120)  2-Phenoxyethyl acrylate, tech. 85%, stab. with 4-methoxyphenol   

  • 48145-04-6

  • 50g

  • 402.0CNY

  • Detail
  • Aldrich

  • (408336)  Ethyleneglycolphenyletheracrylate  contains 75-125 ppm hydroquinone as inhibitor, 0-120 ppm hydroquinone monomethyl as inhibitor

  • 48145-04-6

  • 408336-250ML

  • 905.58CNY

  • Detail
  • Aldrich

  • (408336)  Ethyleneglycolphenyletheracrylate  contains 75-125 ppm hydroquinone as inhibitor, 0-120 ppm hydroquinone monomethyl as inhibitor

  • 48145-04-6

  • 408336-1L

  • 2,781.09CNY

  • Detail

48145-04-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Phenoxyethyl Acrylate

1.2 Other means of identification

Product number -
Other names Acrylic Acid 2-Phenoxyethyl Ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Adhesives and sealant chemicals,Photosensitive chemicals,Solvents (which become part of product formulation or mixture)
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:48145-04-6 SDS

48145-04-6Synthetic route

2-Phenoxyethanol
122-99-6

2-Phenoxyethanol

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

Conditions
ConditionsYield
With dmap; oxo[hexa(trifluoroacetato)]tetrazinc In neat (no solvent) at 80℃; for 24h; Inert atmosphere; Schlenk technique; chemoselective reaction;99%
With toluene-4-sulfonic acid; hydroquinone Entfernen des entstehenden Methanols;
With sulfuric acid; hydroquinone Entfernen des entstehenden Methanols;
2-Phenoxyethanol
122-99-6

2-Phenoxyethanol

acryloyl chloride
814-68-6

acryloyl chloride

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

Conditions
ConditionsYield
at 0℃; for 8h;90%
With copper(I) chloride; sodium carbonate In benzene
2-Phenoxyethanol
122-99-6

2-Phenoxyethanol

ethyl acrylate
140-88-5

ethyl acrylate

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

Conditions
ConditionsYield
With sulfuric acid; hydroquinone Entfernen des entstehenden Aethanols;
With toluene-4-sulfonic acid; hydroquinone Entfernen des entstehenden Aethanols;
2-Phenoxyethanol
122-99-6

2-Phenoxyethanol

sodium carbonate
497-19-8

sodium carbonate

acryloyl chloride
814-68-6

acryloyl chloride

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

Conditions
ConditionsYield
copper(I) chloride In benzene
2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

O,O'-diethyl thiophosphoric acid
2465-65-8

O,O'-diethyl thiophosphoric acid

3-(diethoxy-phosphorylsulfanyl)-propionic acid 2-phenoxy-ethyl ester

3-(diethoxy-phosphorylsulfanyl)-propionic acid 2-phenoxy-ethyl ester

Conditions
ConditionsYield
With 4-methoxy-phenol at 90℃; for 1h; Michael addition;97%
iodobenzene
591-50-4

iodobenzene

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

1-(3-phenyl-2-propenoyloxy)-2-phenoxyethane
90094-75-0

1-(3-phenyl-2-propenoyloxy)-2-phenoxyethane

Conditions
ConditionsYield
With triethylamine; poly{bis[(N-iPr-acrylamide)5-co-((4-vinylphenyl)PPh2)]PdCl2} In toluene at 100℃; for 20h; Heck reaction;97%
O,O-diisopropylphosphorothioic acid
4486-44-6

O,O-diisopropylphosphorothioic acid

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

3-(diisopropoxy-phosphorylsulfanyl)-propionic acid 2-phenoxy-ethyl ester

3-(diisopropoxy-phosphorylsulfanyl)-propionic acid 2-phenoxy-ethyl ester

Conditions
ConditionsYield
With 4-methoxy-phenol at 90℃; for 1h; Michael addition;96%
1-methylindole
603-76-9

1-methylindole

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

2-phenoxyethyl 3-(1-methyl-1H-indol-3-yl)propanoate
1276027-75-8

2-phenoxyethyl 3-(1-methyl-1H-indol-3-yl)propanoate

Conditions
ConditionsYield
With indium(III) bromide In 1,2-dichloro-ethane at 80℃; for 12h; Michael addition; Inert atmosphere; regioselective reaction;93%
2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

2-phenoxyethyl 2-iodoacrylate
1422263-05-5

2-phenoxyethyl 2-iodoacrylate

Conditions
ConditionsYield
With N-iodophthalimide; 3-quinuclidinol In acetonitrile at 20℃; for 24h; Darkness; chemoselective reaction;93%
DL-thiomalic acid
70-49-5

DL-thiomalic acid

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

C15H18O7S

C15H18O7S

Conditions
ConditionsYield
With triethylamine In acetonitrile at 20℃; for 1h;81%
2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

C29H26O8

C29H26O8

Conditions
ConditionsYield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; copper diacetate In N,N-dimethyl-formamide at 110℃; for 12h;79%
1-methyl-1H-indazole
13436-48-1

1-methyl-1H-indazole

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

2-phenoxyethyl (E)-3-(1-methyl-1H-indazol-3-yl)acrylate

2-phenoxyethyl (E)-3-(1-methyl-1H-indazol-3-yl)acrylate

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 1,10-Phenanthroline; copper(II) acetate monohydrate; sodium sulfate Milling;79%
2-ethylbenzaldehyde
22927-13-5

2-ethylbenzaldehyde

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

phenoxyethyl 3-ethyldihydrocinnamate

phenoxyethyl 3-ethyldihydrocinnamate

Conditions
ConditionsYield
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; manganese(III) triacetate dihydrate; silver(I) triflimide In water; 1,2-dichloro-ethane at 130℃; for 16h; Sealed tube; regioselective reaction;71%
N-methylbenzamide
88070-48-8

N-methylbenzamide

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

C19H19NO4

C19H19NO4

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; acetic acid In 1,2-dichloro-ethane at 20℃; for 24h; regioselective reaction;61%
2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

benzonitrile
100-47-0

benzonitrile

2-phenoxyethyl (E)-3-(2-cyanophenyl)acrylate

2-phenoxyethyl (E)-3-(2-cyanophenyl)acrylate

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; silver(I) acetate In acetic acid at 120℃; for 14h; Inert atmosphere; regioselective reaction;59%
2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

ethyl 3,4,5-trimethoxybenzimidate

ethyl 3,4,5-trimethoxybenzimidate

2-phenoxyethyl 2-(3-ethoxy-4,5,6-trimethoxy-1H-isoindol-1-yl)acetate

2-phenoxyethyl 2-(3-ethoxy-4,5,6-trimethoxy-1H-isoindol-1-yl)acetate

Conditions
ConditionsYield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; 1-Adamantanecarboxylic acid In ethanol at 24℃; for 16h; Schlenk technique; Inert atmosphere;58%
2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

4-methoxy-benzimidic acid ethyl ester
829-48-1

4-methoxy-benzimidic acid ethyl ester

2-phenoxyethyl 2-(3-ethoxy-6-methoxy-1H-isoindol-1-yl)acetate

2-phenoxyethyl 2-(3-ethoxy-6-methoxy-1H-isoindol-1-yl)acetate

Conditions
ConditionsYield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; 1-Adamantanecarboxylic acid In ethanol at 24℃; for 16h; Schlenk technique; Inert atmosphere;56%
2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

cyclobutanone O-(4-(trifluoromethyl)benzoyl) oxime

cyclobutanone O-(4-(trifluoromethyl)benzoyl) oxime

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

2-phenoxyethyl 2-(4-chlorobenzoyl)-6-cyanohexanoate

2-phenoxyethyl 2-(4-chlorobenzoyl)-6-cyanohexanoate

Conditions
ConditionsYield
With 3-(2,6-diisopropylphenyl)-5,6,7,8-tetrahydro-4H-cyclohepta[d]thiazol-3-ium perchlorate; sodium hydrogencarbonate; magnesium triflate In N,N-dimethyl acetamide; water at 60℃; for 4h; Inert atmosphere;55%
3-thiophenecarbonitrile
1641-09-4

3-thiophenecarbonitrile

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

bis(2-phenoxyethyl) 3,3'-(3-cyanothiophene-2,4-diyl)(2E,2'E)-diacrylate

bis(2-phenoxyethyl) 3,3'-(3-cyanothiophene-2,4-diyl)(2E,2'E)-diacrylate

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; copper(II) acetate monohydrate In acetic acid; 1,2-dichloro-ethane at 120℃; for 16h; Inert atmosphere; regioselective reaction;45%
2-phenylacrylic acid
492-38-6

2-phenylacrylic acid

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

A

2-phenoxyethyl (Z)-(5-oxo-4-phenyl-5H-furan-2-ylidene)acetate

2-phenoxyethyl (Z)-(5-oxo-4-phenyl-5H-furan-2-ylidene)acetate

B

2-phenoxyethyl (E)-(5-oxo-4-phenyl-5H-furan-2-ylidene)acetate

2-phenoxyethyl (E)-(5-oxo-4-phenyl-5H-furan-2-ylidene)acetate

Conditions
ConditionsYield
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper(II) acetate monohydrate In acetonitrile at 120℃; under 760.051 Torr; Inert atmosphere; Sealed tube; Overall yield = 55 %;A 45%
B 10%
carbon monoxide
201230-82-2

carbon monoxide

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

bis(2-phenoxyethyl) 2-formyl-2-methylpentanedioate

bis(2-phenoxyethyl) 2-formyl-2-methylpentanedioate

Conditions
ConditionsYield
With dicarbonylacetylacetonato rhodium (I); hydrogen; potassium carbonate; 1,4-di(diphenylphosphino)-butane In tetrahydrofuran at 50℃; under 22502.3 Torr; for 18h; Autoclave;40%
1-phenyl-1-pentyne
4250-81-1

1-phenyl-1-pentyne

2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

2-phenoxyethyl 2-phenyl-3-propylcyclobut-2-ene-1-carboxylate

2-phenoxyethyl 2-phenyl-3-propylcyclobut-2-ene-1-carboxylate

Conditions
ConditionsYield
With indium tris(trifluoroacetylacetonate); trimethylsilyl bromide In 1,2-dichloro-ethane at 0 - 20℃; for 2h; Inert atmosphere;40%
2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

Phenylphosphonic acid monoethyl ester amide
5326-06-7

Phenylphosphonic acid monoethyl ester amide

A

(E)-P-ethoxy-P-phenyl-N-(2-phenoxyethyl acrylate) phosphonamide

(E)-P-ethoxy-P-phenyl-N-(2-phenoxyethyl acrylate) phosphonamide

B

(Z)-P-ethoxy-P-phenyl-N-(2-phenoxyethyl acrylate) phosphonamide

(Z)-P-ethoxy-P-phenyl-N-(2-phenoxyethyl acrylate) phosphonamide

Conditions
ConditionsYield
With oxygen; palladium diacetate; copper(I) bromide In tetrahydrofuran at 80℃; under 760.051 Torr; for 5h; stereoselective reaction;A 24%
B 38%
With oxygen; palladium diacetate; nickel dichloride In tetrahydrofuran at 80℃; under 760.051 Torr; for 5h; stereoselective reaction;A 24%
B 38%
2-phenoxyethyl acrylate
48145-04-6

2-phenoxyethyl acrylate

Benzeneacetamide
103-81-1

Benzeneacetamide

(E)-2-phenoxyethyl 3-(2-(2-amino-2-oxoethyl)phenyl)acrylate

(E)-2-phenoxyethyl 3-(2-(2-amino-2-oxoethyl)phenyl)acrylate

Conditions
ConditionsYield
With oxygen; palladium diacetate; trifluoroacetic acid at 100℃; for 36h; regioselective reaction;32%

48145-04-6Relevant articles and documents

Synthesis of randomly aminated polyvinylpyrrolidone and its use in the preparation of hydrolyzable conjugates

Prado, Anselmo Del,Navarro, Rodrigo,Gallardo, Alberto,Elvira, Carlos,Reinecke, Helmut

, p. 35950 - 35958 (2014)

In this work, a versatile synthetic route to functionalize vinylpyrrolidone (VP) with protected or unprotected aliphatic primary amine groups is described for the first time. Using these monomeric precursors polyvinylpyrrolidones (PVPs) with controlled load of side amine groups randomly distributed along the chains have been prepared. These functionalized VP and PVP systems are active molecules highly desirable for further couplings, i.e. they can easily afford the simple preparation of water soluble covalent side chain conjugates onto the PVP backbone. To show the potential of this functionalization, we have prepared functionalized polymers as a controlled release delivering vehicle, employing the bactericide and preservative 2-phenoxyethanol as a hydroxyl-containing model drug. This journal is the Partner Organisations 2014.

Soil fungi inhibiting agent

-

, (2008/06/13)

Soil fungi-inhibiting agent containing as the active ingredient one or more of the compounds represented by the following general formula STR1 wherein I. WHEN BOTH X and Y are oxygen atoms, Z is hydrogen atom, unsubstituted alkyl group, unsubstituted alkenyl group, STR2 (in this case the compound is p-toluene sulfonate), NH2 CH2 -- (in this case the compound is p-toluene sulfonate), acyl group, ClCH2 CONH--, or alkyl group substituted by substituents such as R1 COO--, CH3 COS--, R2 O--, R2 S--, HO--, HOOC--, CH3 CONH--, acyl group, alkoxyacyl group, where R1 is lower-alkyl group or alkenyl group, R2 is lower-alkyl group or benzyl group; Ii. when X is oxygen and Y is sulfur or --NH--, Z is lower alkyl group; Iii. when X is sulfur and Y is oxygen, Z is lower-alkyl group, acetylmethyl group, methoxymethyl group, 2-methyl-1-propynyl group or nitromethyl group; Iv. when X is sulfur and Y is --NH--, Z is lower-alkyl group.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 48145-04-6