482280-36-4Relevant academic research and scientific papers
Reversible cleavage of the C-H bond of aldimine with platinum complexes
Ohtaka, Atsushi,Kato, Naohiro,Kurosawa, Hideo
, p. 5464 - 5466 (2002)
The reversible cleavage of the C-H bond of aldimine with platinum complexes was studied. For the C-H oxidative addition to occur a heteroatom capable of coordinating to the metal center was necessary in the aldimine molecule. Systematic examinations on the thermodynamics and kinetics of both C-H bond oxidative addition and reductive elimination and catalytic application were presented.
