48229-10-3Relevant academic research and scientific papers
1,5-α-D-mannoseptanosides, ring-size isomers that are impervious to α-mannosidase-catalyzed hydrolysis
Boone, Matthew A.,Mcdonald, Frank E.,Lichter, Joseph,Lutz, Stefan,Cao, Rui,Hardcastle, Kenneth I.
supporting information; experimental part, p. 851 - 854 (2009/07/18)
1,5-D-Mannoseptanosyl di-and trisaccharide ring-size isomers of the corresponding mannopyranosyl oligosaccharides have been prepared. Remarkably, these compounds show no inhibition of the α-mannosidase-catalyzed hydrolysis of p-nitrophenyl-α-D-mannopyrano
Mechanistic studies on the stereoselective formation of β-mannosides from mannosyl iodides using α-deuterium kinetic isotope effects
El-Badri, Mohamed H.,Willenbring, Dan,Tantillo, Dean J.,Gervay-Hague, Jacquelyn
, p. 4663 - 4672 (2008/02/10)
(Chemical Equation Presented) Stereoselective synthesis of β-mannosides is one of the most challenging linkages to achieve in carbohydrate chemistry. Both the anomeric effect and the C2 axial substituent favor the formation of the axial glycoside (α-produ
Divergent synthesis of L-sugars and L-iminosugars from D-sugars
Takahashi, Hideyo,Shida, Tomomi,Hitomi, Yuko,Iwai, Yoshinori,Miyama, Namisa,Nishiyama, Kazusa,Sawada, Daisuke,Ikegami, Shiro
, p. 5868 - 5877 (2008/03/11)
An efficient divergent synthesis of L-sugars and L-iminosugars from D-sugars is described. The important intermediate. δ-hydroxyalkoxamate. prepared from D-glucono-/galactono-1,5-lactone, was cyclized under Mitsunobu conditions to give the O-cyclized oxim
Novel 1,6-Stannylenes of Glucose, Galactose and Mannose
Koepper, Sabine,Brandenburg, Anna
, p. 933 - 940 (2007/10/02)
Treatment of 2,3,4-tri-O-benzyl-gluco-, manno-, and -galactopyranose with dibutyltin oxide leads to the 1,6-di-O-stannylene products 2, 5 and 7, whereas no such products are formed by treatment of the 3-O-axially configured ido and allo sugars.Spectroscop
SYNTHESIS OF DERMATAN SULFATE FRAGMENTS: A CHEMICAL SYNTHESIS OF METHYL 2-ACETAMIDO-2-DEOXY-3-O-(α-L-IDOPYRANOSYLURONIC ACID)-4-O-SULFO-β-D-GALACTOPYRANOSIDE DISODIUM SALT AND ITS NON-SULFATED ANALOGUE
Jacquinet, Jean-Claude,Sinay, Pierre
, p. 229 - 254 (2007/10/02)
Methyl 2-azido-2-deoxy-β-D-galactopyranoside was subjected in sequence to isopropylidenation, benzylation, acid hydrolysis, and selective acetylation of HO-4, to give amorphous methyl 4-O-acetyl-2-azido-6-O-benzyl-2-deoxy-β-D-galactopyranoside.Condensatio
