483367-21-1

Basic information

• Product Name: [(C₆H₅)2Si(CH₂N(CH₃)2)2]Rh(CO)2⁽¹⁺⁾*PF₆^(1-)=[(C₆H₅)2Si(CH₂N(CH₃)2)2]Rh(CO)2PF₆
• CAS NO: 483367-21-1
• Molecular Weight: 602.394
• Mol File: 483367-21-1.mol

Chemical Properties

• CAS DataBase Reference: [(C₆H₅)2Si(CH₂N(CH₃)2)2]Rh(CO)2⁽¹⁺⁾*PF₆^(1-)=[(C₆H₅)2Si(CH₂N(CH₃)2)2]Rh(CO)2PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: [(C₆H₅)2Si(CH₂N(CH₃)2)2]Rh(CO)2⁽¹⁺⁾*PF₆^(1-)=[(C₆H₅)2Si(CH₂N(CH₃)2)2]Rh(CO)2PF₆(483367-21-1)
• EPA Substance Registry System: [(C₆H₅)2Si(CH₂N(CH₃)2)2]Rh(CO)2⁽¹⁺⁾*PF₆^(1-)=[(C₆H₅)2Si(CH₂N(CH₃)2)2]Rh(CO)2PF₆(483367-21-1)

Safety Data

• Hazardous Substances Data: 483367-21-1(Hazardous Substances Data)

Upstream product

• 60969-19-9 thallium(I) hexafluorophosphate 
• 483367-19-7 (C₆H₅)2Si(CH₂N(CH₃)2)2 

Relevant articles and documents

Synthesis of the (dialkylamino)borate, [Ph2B(CH2NME2)2]-, affords access to N-chelated rhodium(I) zwitterions

This paper reports the synthesis of the first bis(amino)borate ligand, [Ph2B(CH2NMe2)2]-, an anionic equivalent of tertiary diamines. Anionic [Ph2B(CH2NMe2)2] is an excellent bidentate ligand auxiliary and is used to prepare a series of N-chelated, zwitterionic rhodium(I) complexes.