4840-92-0

Upstream product

• 626-01-7 3-Iodoaniline 
• 2039-86-3 3-bromostyrene 
• 1112-55-6 tetravinylsilane 
• 626-00-6 1,3-Diiodobenzene 
• 696-41-3 m-iodobenzaldehyde 
• 79917-56-9 1-(3-iodophenyl)ethan-1-ol 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 1173697-80-7 2-chloro-1-[4,5-dihydro-5-(3-iodophenyl)-3-isoxazolyl]ethanone 
• 1148045-86-6 1-[4-[4-[4,5-dihydro-5-(3-iodophenyl)-3-isoxazolyl]-2-thiazolyl]-1-piperidinyl]-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone 

Relevant academic research and scientific papers

Diastereoselective C?H Bond Amination for Disubstituted Pyrrolidines

We report herein the improved diastereoselective synthesis of 2,5-disubstituted pyrrolidines from aliphatic azides. Experimental and theoretical studies of the C?H amination reaction mediated by the iron dipyrrinato complex (AdL)FeCl(OEt2) provided a model for diastereoinduction and allowed for systematic variation of the catalyst to enhance selectivity. Among the iron alkoxide and aryloxide catalysts evaluated, the iron phenoxide complex exhibited superior performance towards the generation of syn 2,5-disubstituted pyrrolidines with high diastereoselectivity.

Supported palladium nanoparticles as heterogeneous ligand-free catalysts for the Hiyama C-C coupling of vinylsilanes and halobenzenes leading to styrenes

The Hiyama C-C coupling reaction of a wide range of aryl iodides and vinylsilanes has been performed using ligand-free solid catalysts based on supported palladium nanoparticles. Among the supports tested (Mg, TiO 2, CeO2 and active carbon), the most active catalysts were those in which palladium is supported on MgO and TiO2. Analogous Pt and Au materials were inefficient to promote this reaction. Leaching tests suggest that there is some contribution of dissolved Pd since Pd in solution has been detected and the scavenging test decreases the initial reaction rate. Although the solid Pd catalysts can be reused, it was, however, observed that they undergo a certain deactivation upon use that can be attributed to several factors including the presence of inorganic compounds on the catalyst, Pd leaching or agglomeration of Pd NPs.

FUNGICIDAL AMIDES

Disclosed are compounds of Formulae 1 and 1A (including all geometric and stereoisomers), N-oxides, and salts thereof,(Formula (I, IA), wherein R1, R2, A, G, M, W, Z1, X, J, J1 and n are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula 1 and methods for controlling plant disease caused by a fungal pathogen comprising applying an effective amount of a compound or a composition of the invention.

Potassium organotrifluoroborates: New partners in palladium-catalysed cross-coupling reactions

The preparation of various potassium organotrifluoroborates bearing either aryl, alkenyl, or alkynyl substituents is described. These stable salts are shown to be very efficient partners in palladium-catalysed cross- coupling reactions with arenediazonium salts, affording biaryl and styrene derivatives in high yields.