484002-63-3Relevant academic research and scientific papers
Synthesis, characterization, and reactivity of cationic hydride [HPd(diphosphine)2]+CF3 SO3-, the missing member of the family [HM(dppe)2]+X- (M = Ni, Pd, Pt). DFT QM/MM structural predictions for the [HPd(dppe)2]+ moiety
Aresta, Michele,Dibenedetto, Angela,Amodio, Eliana,Papai, Imre,Schubert, Gabor
, p. 6550 - 6552 (2002)
The synthesis, characterization, and properties of the cationic hydride [HPd(dppe)2]+CF3SO3 -·1/8THF, the missing member of the family [HM(dppe)2]+X- (M = Ni, Pd, Pt), are described. The Pd hydride is not stable in solution and may react as either a proton or a hydride donor. DFT QM/MM calculations of the [HPd(dppe)2]+ moiety have allowed us to predict its structure and reactivity.
