484065-58-9

Basic information

• Product Name: C₁₉H₂₉ClNPPt
• CAS NO: 484065-58-9
• Molecular Weight: 532.953
• Mol File: 484065-58-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₉H₂₉ClNPPt(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₉H₂₉ClNPPt(484065-58-9)
• EPA Substance Registry System: C₁₉H₂₉ClNPPt(484065-58-9)

Safety Data

• Hazardous Substances Data: 484065-58-9(Hazardous Substances Data)

Upstream product

• 240123-21-1 [(κ2-P,N)-2-(N,N-dimethylamino)ethyldiphenylphosphino]dimethylplatinum(II) 
• 105-39-5 chloroacetic acid ethyl ester 

Relevant articles and documents

An NMR study on the reaction of [(κ 2-P,N)-Ph 2PCH2CH2NMe2]PtMe2 with activated chlorocarbons: C-Cl and C-C activation, followed by C-N cleavage of the phosphinoalkylamine ligand and formation of an ylide complex

Reaction of [(κ 2-P,N)-Ph2PCH 2CH2NMe2]PtMe2 with either ethyl chloroacetate or benzyl chloride results in complex reaction mixtures, which were investigated by a combination of NMR techniques. The reactions are initiated by oxidative addition of either the C-Cl bond or of the C-CH 2Cl bond, respectively. The latter is followed by a rearrangement of the intermediate Pt(IV) complex with concomitant C-N bond cleavage of the phosphinoalkylamine ligand and formation of the ylide complexes Pt[CH 2=PPh2(vinyl)](NMe2R)Me2 (R = COOEt or Ph). Graphical abstract: [Figure not available: see fulltext.]