484647-45-2

Upstream product

• 484647-44-1 benzyl 3-O-benzyl-4,6-O-benzylidene-2-O-(p-toluenesulfonyl)-α-D-glucopyranoside 
• 484647-43-0 benzyl 4,6-O-benzylidene-2-O-(p-toluenesulfonyl)-α-D-glucopyranoside 
• 100-51-6 benzyl alcohol 
• 2280-44-6 D-Glucose 
• 79549-73-8 benzyl 4,6-O-(phenylmethylene)-α-D-glucopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 

Downstream Products

• 484647-47-4 benzyl 3,4-di-O-benzyl-6,7-dideoxy-2-O-(p-methoxybenzyl)-α-D-gluco-hept-6-enopyranoside 
• 484647-46-3 benzyl 3,4-di-O-benzyl-2-O-(p-methoxybenzyl)-α-D-glucopiranoside 

Relevant academic research and scientific papers

Total synthesis of desferrisalmycin B

The first total synthesis of a naturally occurring siderophore antibiotic, desferrisalmycin B, is described, and the configuration of the unknown stereocenter is assigned. The synthesis features a synthetic strategy of constructing the novel amino-heptopyranoside component by stereoselective dihydroxylation followed by a Bose-modified Mitsunobu reaction. Through this convergent approach, other members of salmycins should also be synthetically accessible.