485323-14-6Relevant articles and documents
Nucleophilic addition to a Sn(II) imido cubane, [SnNR]4; a new route to heteroleptic stannates
Bond, Andrew D.,Harron, Eilis A.,Lawson, Gavin T.,Mosquera, Marta E.G.,McPartlin, Mary,Wright, Dominic S.
, p. 3525 - 3528 (2002)
Nucleophilic addition to Sn(II) imido cubanes provides a novel route to heteroleptic stannates, as exemplified by the formation of [{Sn(NHmmp)(O'Bu)2}K·thf]2 and [{Sn(MeNCH2CH2NMe)(NHmmp)}Li]∞ (3) from the in situ reactions of the imido Sn(II) cubane [Sn(Nmmp)]4 (1) (mmp = 2-MeO-6-MeC6H3) with 'BuOK and [MeN(Li)CH2CH2(Li)NMe]. This pathway demonstrates that Sn(II) imido cubanes can act as synthons for their aza-stannylene constituents, RN=Sn:.