485756-07-8Relevant academic research and scientific papers
Regioselective synthesis of highly functionalized furans through the RuII-catalyzed [3+2] cycloaddition of diazodicarbonyl compounds
Xia, Likai,Lee, Yong Rok
, p. 3430 - 3442 (2014/06/09)
A novel method for the RuII-catalyzed regioselective synthesis of highly functionalized furans from readily available cyclic and acyclic diazodicarbonyl compounds and terminal alkynes is described. The devised protocol offers a straightforward means to the construction of a variety of diverse furan derivatives through powerful cascade processes, including the formation of ruthenium carbenoid, cyclopropenation, ring-opening metathesis, and cyclization. Copyright
RhII-catalyzed cycloadditions of carbomethoxy iodonium ylides
Batsila, Christina,Kostakis, George,Hadjiarapoglou, Lazaros P
, p. 5997 - 6000 (2007/10/03)
Carbomethoxy iodonium ylides, generated from methyl acetoacetate and methyl malonate, respectively, are exploited in synthesis of cyclopropanes, cyclopropenes as well as various heterocycles.
