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486397-33-5

3-(2,6-DIMETHYLPHENYL)CYCLOHEXANONE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 486397-33-5 Structure

  • Basic information

    1. Product Name: 3-(2,6-DIMETHYLPHENYL)CYCLOHEXANONE
    2. Synonyms: 3-(2,6-DIMETHYLPHENYL)CYCLOHEXANONE
    3. CAS NO:486397-33-5
    4. Molecular Formula: C14H18O
    5. Molecular Weight: 202.29
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 486397-33-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 333.2°C at 760 mmHg
    3. Flash Point: 142.6°C
    4. Appearance: /
    5. Density: 1.013g/cm3
    6. Vapor Pressure: 0.000138mmHg at 25°C
    7. Refractive Index: 1.532
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: 3-(2,6-DIMETHYLPHENYL)CYCLOHEXANONE(CAS DataBase Reference)
    11. NIST Chemistry Reference: 3-(2,6-DIMETHYLPHENYL)CYCLOHEXANONE(486397-33-5)
    12. EPA Substance Registry System: 3-(2,6-DIMETHYLPHENYL)CYCLOHEXANONE(486397-33-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 486397-33-5(Hazardous Substances Data)

486397-33-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 486397-33-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,8,6,3,9 and 7 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 486397-33:
(8*4)+(7*8)+(6*6)+(5*3)+(4*9)+(3*7)+(2*3)+(1*3)=205
205 % 10 = 5
So 486397-33-5 is a valid CAS Registry Number.
InChI:InChI=1/C14H18O/c1-10-5-3-6-11(2)14(10)12-7-4-8-13(15)9-12/h3,5-6,12H,4,7-9H2,1-2H3

486397-33-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-(2,6-dimethylphenyl)cyclohexan-1-one

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:486397-33-5 SDS

486397-33-5Downstream Products

486397-33-5Relevant articles and documents

Synthesis and reactivity of boryloxorhodium complexes. Relevance to intermolecular transmetalation from boron to rhodium in Rh-catalyzed reactions

Nishihara, Yasushi,Nishide, Yasuhiro,Osakada, Kohtaro

, p. 3610 - 3615 (2021)

The synthesis of a dimeric boryloxorhodium complex having the Rh-O-Bpin scaffold from the reaction of [(cod)Rh(OMe)]2or [(cod)Rh(OH)]2with an arylboronate has been achieved. The obtained dirhodium complex is converted into mononuclear complex [(cod)Rh(OBpin)(PPh3)], which reacts with arylboronic acid to afford the complex with an Rh-aryl bondviatransmetalation from boron to rhodium. The dimeric boryloxorhodium complex catalyzes the 1,4-addition of arylboronic acid to cyclohexene-2-one.

New studies of Rh-catalyzed addition of boronic acids under basic conditions in aqueous medium

Amengual, Rémi,Michelet, Véronique,Genêt, Jean-Pierre

, p. 5905 - 5908 (2007/10/03)

Rh-catalyzed C-C bond formation in neat water under basic conditions has been efficiently performed. The addition of various boronic acids to styrene, 2-vinylpyridine, and cyclic α,β-unsaturated ketones has been realized with high selectivity and yield. We have shown that m-TPPTC (tris(m-carboxyphenyl)phosphane trilithium salt) exhibited a higher reactivity compared to TPPTS. These couplings could also be conducted very efficiently under basic and phosphaneless conditions to give functionalized aryl derivatives. The benefits of the additional anionic ligand m-TPPTC lied in the successful recycling experiments of 1,4-addition of phenylboronic acid to cyclohexenone, with no loss of the water-soluble catalyst.

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