486434-01-9Relevant academic research and scientific papers
Novel multichiral diols and diamines by highly stereoselective pinacol coupling of planar chiral [2.2]paracyclophane derivatives
Sergeeva, Elena V.,Rozenberg, Valeria I.,Antonov, Dmitrii Yu.,Vorontsov, Evgenii V.,Starikova, Zoya A.,Fedyanin, Ivan V.,Hopf, Henning
, p. 6944 - 6961 (2005)
The TiCl4/Zn-mediated intermolecular pinacol coupling of the planar chiral carbonyl compounds [2.2]paracyclophane-4-carbaldehyde, 4-acetyl[2.2]paracyclophane (ketone) and the four regioisomeric 5-, 7-, 12- and 13-methoxy[2.2]paracyclophane-4-ca
First stereoselective pinacol coupling in the [2.2]paracyclophane series
Sergeeva, Elena V.,Rozenberg, Valeria I.,Antonov, Dmitrii Yu.,Vorontsov, Evgenii V.,Starikova, Zoya A.,Hopf, Henning
, p. 1121 - 1123 (2007/10/03)
The planar chiral N-arylimines of [2.2]paracyclophane undergo stereoselective pinacol coupling under the action of the Zn/Cu couple in the presence of p-TosOH, thus forming N-aryl substituted 1,2-diamines. The stereoselective formation of the asymmetric c
