488150-69-2

Basic information

• Product Name: Benzoic acid, 3-methyl-2-(2-pentynyloxy)-, methyl ester
• CAS NO: 488150-69-2
• Molecular Formula: C14H16O3
• Molecular Weight: 232.279
• Mol File: 488150-69-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 3-methyl-2-(2-pentynyloxy)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 3-methyl-2-(2-pentynyloxy)-, methyl ester(488150-69-2)
• EPA Substance Registry System: Benzoic acid, 3-methyl-2-(2-pentynyloxy)-, methyl ester(488150-69-2)

Safety Data

• Hazardous Substances Data: 488150-69-2(Hazardous Substances Data)

Upstream product

• 6261-22-9 pent-2-yn-1-ol 
• 23287-26-5 3-methylsalicylic acid methyl ester 

Downstream Products

• 488150-50-1 methyl 2-diazo-3-[3-methyl-2-(2-pentynyloxy)phenyl]-3-oxopropionate 
• 488150-75-0 methyl 3-[3-methyl-2-(2-pentynyloxy)phenyl]-3-oxopropionate 
• 488150-72-7 3-methyl-2-(2-pentynyloxy)benzoic acid 

Relevant articles and documents

Enantioselective tandem formation and [2,3]-sigmatropic rearrangement of cyclic propargylic oxonium ylides catalyzed by dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate]

This paper describes the first examples of catalyst-dependent asymmetric induction in the periselective [2,3]-sigmatropic rearrangement of propargylic oxonium ylides generated by catalytic diazo decomposition. Catalysis of α-diazo-β-keto esters 4a-g using