4884-87-1Relevant articles and documents
Studies towards the taming of the 'carbocation' in the regioselective ring opening of epoxides to allylic alcohols
Chapman, Helen A.,Herbal, Karim,Motherwell, William B.
experimental part, p. 595 - 598 (2010/09/15)
Regioselective isomerisation of epoxides to allylic alcohols can be achieved using p-toluenesulfonic acid in the presence of 1,3- dimethylimidazolidin-2-one. Georg Thieme Verlag Stuttgart.
2-Hydroxy-5,5-dimethylcyclohex-2-en-1-one
Uelkue, Dincer,Tahir, M. Nawaz,Tanyeli, Cihangir,Demir, Ayhan S.,Dikici, Emre
, p. 1998 - 1999 (2007/10/03)
The structure of the title compound, C8H12C2, which is a rearrangement product of the reaction of 6-hydroxy-4,4-dimethylcyclohex-2-en-1-one and 4-dimethylaminopyridine has been identified as 2-hydroxy-5,5-dimethyl-cyclohex-2-en-1-one. The C atom of the six-membered ring connected to the two methyl groups is 0.617 (2) A out of the least-squares plane defined by the other C atoms of the ring. The unit cell consists of discrete molecules with intra- and intermolecular hydrogen bonds.