4889-83-2Relevant academic research and scientific papers
Acidic property of FSM-16
Yamamoto, Takashi,Tanaka, Tsunehiro,Funabiki, Takuzo,Yoshida, Satohiro
, p. 5830 - 5839 (2007/10/03)
Siliceous FSM-16 possesses acid sites to catalyze but-1-ene isomerization to produce but-2-ene (cis/trans = 1.4-1.7) at 323 K and 2,6,6- trimethylbicyclo[3.1.1]hept-2-ene (α-pinene) isomerization at 303 K. Catalytic activity was dependent upon heat treatment and reached a maximum at 673 K. The maximum acid strength was invariably H0 = -3.0 independent of the pretreatment temperatures. The acidity was much reduced by calcination at higher temperatures, but restored by water treatment at 353 K as long as the FSM-16 retained its structure.
