4920-73-4Relevant articles and documents
Concurrent cyclopropanation by carbenes and carbanions
Moss, Robert A.,Tian, Jingzhi
, p. 8960 - 8961 (2005)
The generation of phenylhalocarbenes in the presence of varying quantities of halide ions and electron-poor alkenes affords concurrent cyclopropanation of the alkenes by an equilibrating mixture of phenylhalocarbenes and phenylhalomethide carbanions, whic
ABSOLUTE RATE CONSTANTS FOR THE ADDITIONS OF HALOPHENYLCARBENES TO ALKENES; A REACTIVITY-SELECTIVITY RELATION
Cox, D. Phillip,Gould, Ian R.,Hacker, Nigel P.,Moss, Robert A.,Turro, Nicholas J.
, p. 5313 - 5316 (2007/10/02)
The absolute rate constants determined for the additions of FCPh, ClCPh, and BrCPh to Me2C=CMe2, Me2C=CHMe, trans-MeCH=CHEt, and n-BuCH=CH2, appear to follow a reactivity/selectivity pattern of the "normal" (inverse) type.