492447-67-3Relevant academic research and scientific papers
Novel phosphine- and phosphite-induced imido migration to a cyclopentadienyl ring in an imido-bridged cobaltadithiolene complex
Nomura, Mitsushiro,Takayama, Chikako,Janairo, Gerardo C.,Sugiyama, Toru,Yokoyama, Yasuo,Kajitani, Masatsugu
, p. 195 - 198 (2008/10/08)
The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp ring in a tosylimido-bridged cobaltadithiolene complex was investigated, and a probable intermediate was isolated and characterized. The presence of a large excess of PPh3 causes the formation of the imido- and phosphine-substituted Cp complex.
