492453-48-2

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 492453-60-8 3-(6-chloro-3-formyl-1,5,8-trimethoxy-naphthalen-2-yl)-4-hydroxymethyl-2-methoxy-6-methyl-benzoic acid methyl ester 
• 492453-59-5 3-(6-chloro-3-formyl-1,5,8-trimethoxy-naphthalen-2-yl)-2-methoxy-4-methoxymethoxymethyl-6-methyl-benzoic acid methyl ester 

Downstream Products

• 492453-51-7 3-[3-(bis-benzyloxy-methyl)-6-chloro-1,5,8-trimethoxy-naphthalen-2-yl]-4-formyl-2-methoxy-6-methyl-benzoic acid methyl ester 
• 492453-50-6 3-[3-(bis-benzyloxy-methyl)-6-chloro-1,5,8-trimethoxy-naphthalen-2-yl]-4-hydroxymethyl-2-methoxy-6-methyl-benzoic acid methyl ester 
• 492453-49-3 3-[3-(bis-benzyloxy-methyl)-6-chloro-1,5,8-trimethoxy-naphthalen-2-yl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-2-methoxy-6-methyl-benzoic acid methyl ester 

Relevant academic research and scientific papers

Semi-pinacol strategy for constructing B-ring of pradimicin-benanomicin antibiotics

Semi-pinacol cyclization of compound 8, having an acetal and an aldehyde substituent, was achieved by employing SmI2 and BF3·OEt2, leading to the highly stereoselective formation of cyclized product 9. The vicinal diol in