492455-74-0Relevant academic research and scientific papers
Diastereoselective synthesis of β-substituted α-hydroxyphosphinates through hydrophosphinylation of α-heteroatom-substituted aldehydes
Yamagishi, Takehiro,Kusano, Takanori,Kaboudin, Babak,Yokomatsu, Tsutomu,Sakuma, Chiseko,Shibuya, Shiroshi
, p. 767 - 772 (2003)
The diastereoselective synthesis of β-substituted α-hydroxyphosphinates was achieved by hydrophosphinylation of α-oxy aldehydes and α-amino aldehydes with ethyl allylphosphinate catalyzed by lithium phenoxide.
Stereoselective synthesis of β-amino-α-hydroxy(allyl)phosphinates and an application to the synthesis of a building block for phosphinyl peptides
Yamagishi, Takehiro,Kusano, Takanori,Yokomatsu, Tsutomu,Shibuya, Shiroshi
, p. 1471 - 1474 (2007/10/03)
Hydrophosphinylation of N,N-dibenzyl-α-amino aldehydes with ethyl allylphosphinate in the presence of (S)-ALB afforded anti-β-amino-α-hydroxy(allyl)phosphinates in high diastereoselectivity. The hydrophosphinylation product was transformed to a potentiall
