492456-08-3

Upstream product

• 501-53-1 benzyl chloroformate 
• 994-30-9 triethylsilyl chloride 
• 111060-65-2 (S)-2-(dibenzylamino)-4-methylpentanal 
• 492455-81-9 ethyl allyl((1R,2S)-2-dibenzylamino-1-hydroxy-4-methylpentyl)phosphinate 
• 492456-03-8 Allyl-((1R,2S)-2-dibenzylamino-4-methyl-1-triethylsilanyloxy-pentyl)-phosphinic acid ethyl ester 
• 492456-06-1 ((1R,2S)-2-Dibenzylamino-4-methyl-1-triethylsilanyloxy-pentyl)-(2-oxo-ethyl)-phosphinic acid ethyl ester 

Downstream Products

• 492456-10-7 [((1R,2S)-2-Benzyloxycarbonylamino-1-hydroxy-4-methyl-pentyl)-ethoxy-phosphinoyl]-acetic acid methyl ester 

Relevant academic research and scientific papers

Stereoselective synthesis of β-amino-α-hydroxy(allyl)phosphinates and an application to the synthesis of a building block for phosphinyl peptides

Hydrophosphinylation of N,N-dibenzyl-α-amino aldehydes with ethyl allylphosphinate in the presence of (S)-ALB afforded anti-β-amino-α-hydroxy(allyl)phosphinates in high diastereoselectivity. The hydrophosphinylation product was transformed to a potentiall