493021-10-6Relevant articles and documents
Studies Directed toward Asymmetric Synthesis of Cardioactive Steroids via Anionic Polycyclization
Yang, Zhixiang,Shannon, Dean,Truong, Vouy-Linh,Deslongchamps, Pierre
, p. 4693 - 4696 (2007/10/03)
(Matrix Presented) The use of anionic polycyclization (AP) in constructing the steroidal backbone of cardenolides was investigated. The reaction of 2-carbomethoxy-2-cyclohexenone I with the enolate of Nazarov reagent II gave, after decarboxylation and ald