4936-89-4Relevant academic research and scientific papers
Syntheses and characterization of mononuclear Zn(II), Cd(II) and Hg(II) complexes of 2-[(3,5-dibromo-2-hydroxy-benzylidene)-amino]-2-hydroxymethyl-propane-1,3-diol: Photoluminescence properties and DFT study
Chatterjee, Sourav,Majumder, Ishani,Chakraborty, Aratrika,Shukla, Madhulata,Chattopadhyay, Tanmay
, p. 159 - 167 (2018)
A new Schiff-base ligand HL ((2-[(3,5-dibromo-2-hydroxy-benzylidene)-amino]-2-hydroxymethyl-propane-1,3-diol)) was obtained by the 1:1 condensation of 1,3-dibromo salicylaldehyde and (tris hydroxy methyl) amino methane. Then three new complexes, [Zn(L)su
Imine or Enamine? Insights and Predictive Guidelines from the Electronic Effect of Substituents in H-Bonded Salicylimines
Cintas, Pedro,Martínez, R. Fernando,Matamoros, Esther,Palacios, Juan C.
supporting information, p. 5838 - 5862 (2020/05/20)
Imine and enamine bonds decorate the skeleton of numerous reagents, catalysts, and organic materials. However, it is difficult to isolate at will a single tautomer, as dynamic equilibria occur easily, even in the solid state, and are sensitive to electronic and steric effect, including π-conjugation and H-bonding. Here, using as model Schiff bases generated from salicylaldehydes and TRIS in a set of linear free energy relationships (LFER), we disclose how the formation of either imines or enamines can be controlled and provide a comprehensive framework that captures the structural underpinning of this prediction. This work highlights the potentiality of tailor-made designs en route to compounds with desirable functionality.
Inner complex compounds of dioxomolybdenum(VI) with o-oxyazomethines, derivatives of substituted salicylaldehydes and tris(hydroxymethyl)aminomethane. crystal structures of two complexes [MoO(L)] · CH3OH; L = Z-substituted salicylalimines, Z =
Abramenko,Churakov,Sergienko,Mikhailov,Surazhskaya
, p. 553 - 559 (2013/10/22)
Ten new dioxomolybdenum(VI) compounds with o-oxyazomethines, derivatives of substituted salicylaldehydes (I-X) and tris(hydroxymethyl)aminomethane, are synthesized. The structures of two of them, [MoO2(L)] · CH3OH; L = Z-substituted
