494227-36-0

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Basic information

Product Name: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
Synonyms: MANDYPHOS SL-M003-1;(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE;(R,R)-1,1'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE;(S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-DI[BIS(3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINO]FERROCENE;(aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis{bis[3,5-bis(trifl;(S,S)-(-)-2,2'-Bis((R)-(N,N-dimethylamino)-(phenyl)methyl)-1,1'-di(bis(3,5-trifluoromethylphenyl)phosphino)ferrocene;(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene,min.97%;(r,r)-1,1'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2'-bis[(r)-α-(dimethylamino)benzyl]ferrocene (acc to cas)
CAS NO:494227-36-0
Molecular Formula: C60H42F24FeN2P2 10*
Molecular Weight: 1364.74
EINECS: N/A
Product Categories: Chiral Phosphine;Ferrocene Series;Mandyphos Series
Mol File: 494227-36-0.mol
Article Data: 0

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: orange-red/solid
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
Stability: store cold
CAS DataBase Reference: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE(CAS DataBase Reference)
NIST Chemistry Reference: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE(494227-36-0)
EPA Substance Registry System: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE(494227-36-0)

Safety Data

Hazard Codes: N/A
Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 494227-36-0(Hazardous Substances Data)

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Factory Price OLED 99% 494227-36-0 (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl) phosphino]ferrocene Manufacturer
Cas No: 494227-36-0
USD $ 0.1-0.1 / Gram
1 Gram
100 Metric Ton/Year
Xi'an Xszo Chem Co., Ltd.
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(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl) phosphino]ferrocene CAS 494227-36-0 In stock
Cas No: 494227-36-0
USD $ 1.0-1.0 / Metric Ton
1 Metric Ton
5 Metric Ton/Day
Chemwill Asia Co., Ltd.
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(Alphar,Alphar)-1,1'-Bis[Alpha-(Dimethylamino)Benzyl]-(S,S)-,2'-Bis[Bis[3,5-Bis(Trifluoromethyl)Phenyl]Phosphino]Ferrocene
Cas No: 494227-36-0
USD $ 1.0-1.0 / Kilogram
1 Kilogram
2000 Metric Ton/Year
Henan Sinotech Import&Export Corporation
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE CAS:494227-36-0
Cas No: 494227-36-0
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Qingdao Beluga Import and Export Co., LTD
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(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl) phosphino]ferrocene
Cas No: 494227-36-0
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100 Gram
100 Kilogram/Month
Triumph International Development Limilted
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(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl) phosphino]ferrocene
Cas No: 494227-36-0
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SHANGHAI T&W PHARMACEUTICAL CO., LTD.
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(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl) phosphino]ferrocene
Cas No: 494227-36-0
USD $ 100.0-100.0 / Gram
10 Gram
500 Kilogram/Month
Zibo Hangyu Biotechnology Development Co., Ltd
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(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl) phosphino]ferrocene
Cas No: 494227-36-0
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Zibo Dorne chemical technology co. LTD
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(1R,1'R)-1,1'-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2'-bis[(R)-(dimethylamino)phenylmethyl]ferrocene
Cas No: 494227-36-0
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Suzhou Health Chemicals Co., Ltd.
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
Cas No: 494227-36-0
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BOC Sciences
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494227-36-0 Usage

Reaction

Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates. Ligand for Rh-catalyzed hydrogenation of αand β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3diketones. Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives. Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones. Ligand for Cu-catalyzed enantioselective hydroboration of αand β-unsaturated esters and nitriles.

Chemical Properties

Orange powder

Check Digit Verification of cas no

The CAS Registry Mumber 494227-36-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,9,4,2,2 and 7 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 494227-36:
(8*4)+(7*9)+(6*4)+(5*2)+(4*2)+(3*7)+(2*3)+(1*6)=170
170 % 10 = 0
So 494227-36-0 is a valid CAS Registry Number.

InChI:InChI=1/2C30H21F12NP.Fe/c2*1-43(2)26(17-7-4-3-5-8-17)24-9-6-10-25(24)44(22-13-18(27(31,32)33)11-19(14-22)28(34,35)36)23-15-20(29(37,38)39)12-21(16-23)30(40,41)42;/h2*3-16,26H,1-2H3;/t2*26-;/m11./s1

494227-36-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name	(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl) phosphino]ferrocene, min. 97%

1.2 Other means of identification

Product number	-
Other names	MANDYPHOS SL-M003-1

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

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