494860-46-7

Upstream product

• 17042-40-9 4-methoxyphenyl 2,3,4,6-tetra-O-acetyl-1-α-D-mannopyranoside 
• 530-26-7 D-Mannose 
• 28541-75-5 p-methoxyphenyl α-D-mannopyranoside 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 494860-47-8 (1R,4R,5S,6R)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5,6-tris-methoxymethoxy-cyclohex-2-enol 
• 494860-30-9 (4R,5S,6S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5,6-tris-methoxymethoxy-cyclohex-2-enone 
• 494860-32-1 tert-Butyl-((3R,4R,5S,6R)-3-methoxy-4,5,6-tris-methoxymethoxy-cyclohex-1-enylmethoxy)-diphenyl-silane 
• 494860-25-2 (3S,4S,5R,6R)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-3,4,5-tris-methoxymethoxy-tetrahydro-pyran-2-one 
• 494860-23-0 tert-Butyl-diphenyl-[(2R,3R,4S,5S,6R)-3,4,5-tris-methoxymethoxy-6-(4-methoxy-phenoxy)-tetrahydro-pyran-2-ylmethoxy]-silane 

Relevant academic research and scientific papers

Serendipitous one-pot synthesis of chiral dienes from pyranosidic 2,4-bistriflates

Attempted nucleophilic displacements of L-rhamnosyl 2,4-bistriflates led to serendipitous formation of a chiral diene via competing cascade eliminations. The reaction also followed the same pathway with D-rhamnosyl and D-mannosyl 2,4-bistriflates substrat

Synthesis and evaluation of transition-state analogue inhibitors of α-1,3-fucosyltransferase

Mimics of the geometry or charge of the fucose moiety of GDP-fucose in the transition state of fucosyltransferase-catalyzed reactions, compounds 1-3 are good competive inhibitors of α-1,3-fucosyltransferases V and VI with Ki values between 6 an