49540-34-3Relevant academic research and scientific papers
Reactions of grignard reagents with nitrous oxide
Tskhovrebov, Alexander G.,Solari, Euro,Scopelliti, Rosario,Severin, Kay
supporting information, p. 2405 - 2408 (2014/06/10)
The chemical activation of nitrous oxide (N2O) can be achieved by organocalcium, organosodium, and organolithium compounds. Grignard reagents, on the other hand, are believed to be inert. We demonstrate that this generalization is not correct. Some aliphatic Grignard reagents undergo a rapid conversion when subjected to an atmosphere of N2O. Hydrazones are the main reaction products.
1,1,4,4,-TETRAALKYLAMIDAZINES. SYNTHESIS OF MONOALKYLHYDRAZINES
Zelenin, K. N.,Khrustalev, V. A.,Sergutina, V. P.
, p. 244 - 247 (2007/10/02)
A series of 1,1,4,4,-tetraalkylamidazines were synthesized.Their IR, UV, and 1H and 13C NMR spectra were investigated, and the characteristics of their stereochemical structure are discussed.Amidazines are alkylated by the action of alkyl iodides at the imine nitrogen atom.Alkaline cleavage of the alkyl iodide derivatives is a method for the production of monoalkylhydrazines.
