49560-35-2Relevant articles and documents
On the possibility of determining stereochemistry in acyclic polyhydroxylated compounds by the combined vicinal coupling constant/molecular mechanics method. A test with alditol peracetates
Osawa, Eiji,Imai, Keisuke,Fujiyoshi-Yoneda, Teruyo,Jaime, Carlos,Ma, Philip,Masamune, Satoru
, p. 4579 - 4590 (2007/10/02)
Relative configurations of multiple asymmetric centers in alditol peracetates can be determined with 92% confidence from vicinal H/H coupling constants along backbone chain and molecular mechanics calculations.
D-GLUCOPYRANOSYL PHENYLSULFONES: THEIR USE IN A STEREOCONTROLLED SYNTHESIS OF CIS 2,6-DISUBSTITUTED TETRAHYDROPYRANS (β-D-C-GLYCOSIDES)
Beau, Jean-Marie,Sinay, Pierre
, p. 6189 - 6192 (2007/10/02)
The lithiated anion derived from 3,4,6-tri-O-t-butyldimethylsilyl-2-deoxy-α,β-D-glucopyranosyl phenylsulfones 1 reacts with various electrophiles leading to alkylated products, precursors of β-D-C-glycosides 5a-g after stereocontrolled desulfonylation and
