496849-16-2Relevant academic research and scientific papers
Modulating weak interactions for molecular recognition: A dynamic combinatorial analysis for assessing the contribution of electrostatics to the stability of CH-π bonds in water
Jiménez-Moreno, Ester,G?mez, Ana M.,Bastida, Agatha,Corzana, Francisco,Jiménez-Oses, Gonzalo,Jiménez-Barbero, Jesús,Asensio, Juan Luis
, p. 4344 - 4348 (2015/04/14)
Electrostatic and charge-transfer contributions to CH-π complexes can be modulated by attaching electron-withdrawing substituents to the carbon atom. While clearly stabilizing in the gas phase, the outcome of this chemical modification in water is more difficult to predict. Herein we provide a definitive and quantitative answer to this question employing a simple strategy based on dynamic combinatorial chemistry.
SELECTIVE OXIDATION OF CARBOHYDRATES
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, (2014/01/09)
The invention relates to the field of carbohydrate chemistry. Provided is a process for the regioselective oxidation of a single secondary hydroxy function of a carbohydrate substrate comprising two or more secondary hydroxy functions, comprising contacting the carbohydrate substrate in a solvent in the presence of a transition metal catalyst complex with an oxidizing agent to yield a mono-oxidized carbohydrate.
Catalytic regioselective oxidation of glycosides
Jaeger, Manuel,Hartmann, Marcel,De Vries, Johannes G.,Minnaard, Adriaan J.
, p. 7809 - 7812 (2013/08/23)
Discrimination among equals: A catalytic method for the selective oxidation of unprotected glycosides, both monosaccharides and disaccharides, has been developed. The resulting ketosaccharides are isolated in moderate to excellent yields. This approach provides a basis for protecting-group-free synthetic transformations of carbohydrates. Copyright
