496949-27-0

Basic information

• Product Name: Cyclohexanecarboxaldehyde, 4-(1E)-1-propenyl-, trans- (9CI)
• Synonyms: Cyclohexanecarboxaldehyde, 4-(1E)-1-propenyl-, trans- (9CI)
• CAS NO: 496949-27-0
• Molecular Formula: C10H16O
• Molecular Weight: 152.23344
• Product Categories: ALDEHYDE
• Mol File: 496949-27-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclohexanecarboxaldehyde, 4-(1E)-1-propenyl-, trans- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarboxaldehyde, 4-(1E)-1-propenyl-, trans- (9CI)(496949-27-0)
• EPA Substance Registry System: Cyclohexanecarboxaldehyde, 4-(1E)-1-propenyl-, trans- (9CI)(496949-27-0)

Safety Data

• Hazardous Substances Data: 496949-27-0(Hazardous Substances Data)

Upstream product

• 211995-95-8 cis-4-[(Z)-prop-1-en-1-yl]cyclohexylmethyl pivaloate 
• 211995-86-7 cis-4-(pivaloyloxymethyl)cyclohexanecarbaldehyde 
• 211995-97-0 cis-4-[(Z)-prop-1-en-1-yl]cyclohexanemethanol 
• 211995-96-9 trans-4-[(Z)-prop-1-en-1-yl]cyclohexylmethyl pivaloate 
• 211995-87-8 trans-4-(pivaloyloxymethyl)cyclohexanecarbaldehyde 
• 19145-96-1 diethyl cyclohexane-trans-1,4-dicarboxylate 
• 3236-48-4 trans-1,4-Cyclohexanedimethanol 
• 211995-98-1 trans-4-[(Z)-prop-1-en-1-yl]cyclohexanemethanol 
• 3236-47-3 (1s,4s)-cyclohexane-1,4-diyldimethanol 

Relevant articles and documents

Intramolecular Cyclization of 4-[3-(Trimethylsilyl)prop-1-en-1-yI]-cyclohexanecarbaldehyde with Loss of Formyl Carbon

Treatment of cis- and trans-4-[3-(trimethylsilyl)prop-1-en-1-yl]cydohexanecarbaldehyde (2a and 2b) with tetrabutylammonium fluoride in dilute tetrahydrofuran afforded 7-vinylbicyclo(2.2.1]heptan-1-ol (3), the same product obtained from 4-[3-(trimethylsilyl)prop-1-en-1-yl]cyclohexanone (1). It was found that oxidative deformyhition of 2a, b to 1 takes place under basic conditions before the cyclization to 3. It was also shown that cyclization of allylsilane with carbonyl does not proceed via an eclipsed conformation.