497144-19-1

Basic information

• Product Name: 9-Oxa-2,4-diaza-10-siladodeca-2,6-dienoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-7,11,11-trimethyl-10,10-diphen yl-, 1,1-dimethylethyl ester, (6E)-
• CAS NO: 497144-19-1
• Molecular Formula: C32H47N3O5Si
• Molecular Weight: 581.828
• Mol File: 497144-19-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 9-Oxa-2,4-diaza-10-siladodeca-2,6-dienoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-7,11,11-trimethyl-10,10-diphen yl-, 1,1-dimethylethyl ester, (6E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Oxa-2,4-diaza-10-siladodeca-2,6-dienoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-7,11,11-trimethyl-10,10-diphen yl-, 1,1-dimethylethyl ester, (6E)-(497144-19-1)
• EPA Substance Registry System: 9-Oxa-2,4-diaza-10-siladodeca-2,6-dienoic acid, 3-[[(1,1-dimethylethoxy)carbonyl]amino]-7,11,11-trimethyl-10,10-diphen yl-, 1,1-dimethylethyl ester, (6E)-(497144-19-1)

Safety Data

• Hazardous Substances Data: 497144-19-1(Hazardous Substances Data)

Upstream product

• 929897-53-0 4-(tert-butyl-diphenyl-silanyloxy)-3-methyl-but-2-enylamine 
• 207857-15-6 1,3-di(tert-butyloxycarbonyl)-2-(trifluoromethylsulfonyl)guanidine 
• 929897-51-8 (2E)-4-{[(tert-butyl)diphenylsilyl]oxy}-3-methylbut-2-en-1-ol 
• 497144-17-9 (E)-ethyl 4-(tert-butyl-diphenyl-silanyloxy)-3-methyl-but-2-enoate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 118171-02-1 1-(tert-butyldiphenylsilyloxy)-2-propanone 
• 286955-44-0 tert-butyl [N-(tert-butoxycarbonyl)-N'-(trifluoroacetyl)carbamimidoyl]carbamate 
• 497144-18-0 (4-azido-2-methyl-but-2-enyloxy)-tert-butyl-diphenyl-silane 

Relevant articles and documents

Asymmetric total synthesis of martinelline and martinellic acid

Herein, we describe the first asymmetric total synthesis of (-)-martinelline ((-)-2) and the second total synthesis of (-)-martinellic acid ((-)-1) by employing a tandem Mukaiyama-Mannich reaction/aminal cyclization as the key step. The Royal Society of C