497182-23-7

Basic information

• Product Name: allyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1-4)-2-O-benzoyl-α-L-rhamnopyranoside
• Synonyms: allyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1-4)-2-O-benzoyl-α-L-rhamnopyranoside
• CAS NO: 497182-23-7
• Molecular Weight: 830.972
• Mol File: 497182-23-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: allyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1-4)-2-O-benzoyl-α-L-rhamnopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: allyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1-4)-2-O-benzoyl-α-L-rhamnopyranoside(497182-23-7)
• EPA Substance Registry System: allyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1-4)-2-O-benzoyl-α-L-rhamnopyranoside(497182-23-7)

Safety Data

• Hazardous Substances Data: 497182-23-7(Hazardous Substances Data)

Upstream product

• 707-07-3 orthobenzoic acid trimethyl ester 
• 236731-58-1 allyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1->4)-α-L-rhamnopyranoside 
• 100639-25-6 allyl 2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 236731-57-0 allyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1->4)-2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 90357-89-4 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl trichloroacetimidate 

Downstream Products

• 497182-24-8 allyl 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside 
• 686767-41-9 allyl (2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1->4)-2-O-benzoyl-3-O-chloroacetyl-α-L-rhamnopyranoside 
• 502698-49-9 (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1-3)-[(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1-4)]-2-O-benzoyl-L-rhamnopyranosyl trichloroacetimidate 
• 672907-44-7 allyl (3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside 
• 724764-04-9 2-azidoethyl 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranosyl-(1->3)-2-(acetylamino)-2-deoxy-4,6-isopropylidene-β-D-glucopyranoside 
• 724764-05-0 2-azidoethyl 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranosyl-(1->3)-2-(acetylamino)-2-deoxy-β-D-glucopyranoside 
• 724763-95-5 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-L-rhamnopyranosyl trichloroacetimidate 
• 724764-10-7 allyl 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl-(1->2)-3,4-di-O-benzyl-α-L-rhamnopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside 
• 672907-39-0 allyl (2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->2)-(3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranoside 
• 502698-58-0 allyl (2-O-acetyl-3,4-di-O-benzyl-α-L-rhamnopyranosyl)-(1-3)-[(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1-4)]-2-O-benzoyl-α-L-rhamnopyranoside 
• 497182-22-6 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranosyl trichloroacetimidate 
• 824939-60-8 2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl-(1->3)-[2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl-(1->4)]-2-O-benzoyl-α-L-rhamnopyranose 

Relevant articles and documents

Blockwise Approach to Fragments of the O-Specific Polysaccharide of Shigella flexneri Serotype 2a: Convergent Synthesis of A Decasaccharide Representative of a Dimer of the Branched Repeating Unit

The D′A′B′(E′)C′DAB(E)C decasaccharide representative of a dimer of a frame-shifted pentasaccharide repeating unit of the O-specific polysaccharide of Shigella flexneri 2a was synthesized as its methyl glycoside by condensing a pentasaccharide donor (D′A′B′ (E′)C′) and a pentasaccharide acceptor (DAB(E)C-OMe). Several convergent routes to these two building blocks, involving either the AB linkage or the BC linkage as the disconnection site, were evaluated in comparison to the linear strategy. The latter was preferred. It is based on the use of the trichloroacetimidate chemistry. The target branched oligosaccharide was designed to probe the recognition at the molecular level of the natural polysaccharide by protective monoclonal antibodies.