497227-01-7

Upstream product

• 74-88-4 methyl iodide 
• 194410-26-9 3-(6'-O-acetyl-2',3',4'-tri-O-benzyl-α-D-glucopyranosyl)-1-propene 
• 82614-11-7 [(2R,3R,4R,5S,6R)-3,4,5-tris(benzyloxy)-6-(prop-2-en-1-yl)oxan-2-yl]methanol 

Downstream Products

• 497227-02-8 methyl 2,6-anhydro-3,4,5-tri-O-benzyl-7-deoxy-D-glycero-L-glucoocturonate 

Relevant academic research and scientific papers

Synthesis of sugar azido or amino esters and their use as building blocks for the preparation of saccharide nucleosides

Several sugar azido or amino esters bearing an α- or a β-C-D-glucopyranosyl backbone have been prepared by TMSOTf/Ac2O-mediated α-C-glycosylation with concurrent selective removal of the primary benzyl group or selective acetolysis of the primary benzyl group of β-C-glycoside as key steps. Such structures have been successfully used as scaffolds for the synthesis of novel saccharide nucleosides. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.