49752-09-2Relevant academic research and scientific papers
Rhodium Catalysts with a Chiral Cyclopentadienyl Ligand Derived from Natural R-Myrtenal
Kolos, Andrey V.,Nelyubina, Yulia V.,Perekalin, Dmitry S.,Pototskiy, Roman A.
, p. 6019 - 6025 (2020/09/21)
A new chiral cyclopentadiene CpmyrH was synthesized from the natural terpene (R)-myrtenal in 5 steps and about 40 % total yield. The key step was the reaction of vinyl-dibromocyclopropane derivative with MeLi which provided the diene Cpmyr
Molecular Modelling: A Contribution to the Understanding of the Catalytic Enantioselective Hydrovinylation of Styrene
Angermund, Klaus,Eckerle, Anette,Lutz, Frank
, p. 488 - 502 (2007/10/02)
The hydrovinylation of styrene can be catalyzed by the addition of phosphane-modified Ni(II) compounds with high reactivity and enantioselectivity if the azaphospholene 1 is used as P-component of the catalysts.Until recently the industrial applications o
