49774-14-3Relevant academic research and scientific papers
Selective Reductions of N,N-Bis{chloro(aryl)-phosphino}-amines Yielding Three-, Five-, Six-, and Eight-Membered Cyclic Azaphosphanes
H?hne, Martha,Joksch, Markus,Konieczny, Katharina,Müller, Bernd H.,Spannenberg, Anke,Peulecke, Normen,Rosenthal, Uwe
, p. 4298 - 4309 (2017)
To date, a plethora of λ3-P nitrogen-containing compounds is known. A large number of them are used as ligands in coordination chemistry and homogeneous catalysis. PN-containing compounds tend to build up cyclic moieties, which have received less attention in regard to their application as ligands in transition metal chemistry. Hence, different dehalogenation reactions of N,N-bis{chloro(aryl)-phosphino}-amines have been developed to synthesize different P-N-P containing cyclic compounds. Their coordination behavior to group VI transition metal carbonyls was explored.
Nitrogen-Phosphorus(III)-Chalcogen Macrocycles for the Synthesis of Polynuclear Silver(I) Sandwich Complexes
Yogendra, Sivathmeehan,Hennersdorf, Felix,Weigand, Jan J.
, p. 8698 - 8704 (2017)
The synthesis of inorganic N-P(III)-Ch-based macrocycles [-PhP-NMe-PPh-Ch-]2 (8Ch; Ch = S, Se) is presented by incorporating two nitrogen, two chalcogen, and four phosphorus atoms. The macrocycles are conveniently obtained via the cy
