497838-01-4Relevant academic research and scientific papers
Lewis acid-catalyzed nucleophilic substitutions of propargylic and allylic silyl ethers with enol silyl ethers
Ishikawa, Teruhiko,Aikawa, Toshiaki,Mori, Yumiko,Saito, Seiki
, p. 51 - 54 (2007/10/03)
(Matrix presented) Nucleophilic reactions of various enol silyl ethers with carbocation species generated from propargyl silyl ethers by the action of a Lewis acid have been developed. The present method is highly useful for the introduction of allenic or
Rearrangement of 1-(1-alkynyl)cyclopropanols to 2-cyclopentenones via their hexacarbonyldicobalt complexes. A new use of alkyne-CO2(CO)6 complexes in organic synthesis
Iwasawa, Nobuharu,Matsuo, Takeshi,Iwamoto, Mari,Ikeno, Taketo
, p. 3903 - 3914 (2007/10/03)
A novel rearrangement of 1-(1-alkynyl)cyclopropanols to 2-cyclopenten- 1-ones proceeded on complexation of their alkynyl part with octacarbonyldicobalt (Co2(CO8)). 1-(1-Alkynyl)cyclopropanols with a wide range of substituents on thei
