497845-35-9Relevant academic research and scientific papers
Total syntheses of angular [7]-, [8]-, and [9]phenylene by triple cobalt-catalyzed cycloisomerization: Remarkably flexible heliphenes
Han, Sangdon,Anderson, D. Ryan,Bond, Andrew D.,Chu, Hiufung V.,Disch, Raymond L.,Holmes, Daniel,Schulman, Jerome M.,Teat, Simon J.,Vollhardt, K. Peter C.,Whitener, Glenn D.
, p. 3227 - 3230 (2007/10/03)
Six of the final cyclobutadiene rings in angular [8]phenylene and [9]phenylene (1) are closed in an unprecedented cobalt-catalyzed triple cyclization of appropriate nonaynes. These strained products are the largest known phenylenes and display unusual con
