4984-12-7Relevant academic research and scientific papers
Metal ions do not play a direct role in the formation of carbon-carbon triple bonds during reduction of trihaloalkyls by CrII or V II
Levy, Ophir,Bino, Avi
supporting information, p. 15944 - 15947 (2013/02/23)
Carbyne radicals: Reactions of trihaloalkyl compounds with Cr2+ or V2+ in aqueous solutions yield alkynes and other products. Stepwise halogen abstractions from the trihaloalkyls form alkyl carbyne triradicals in solution. These radicals undergo coupling reactions, producing triply bonded alkyne molecules (see scheme). This process is not metal-assisted and does not occur in the coordination sphere of the metal ions.
Unimolecular reactions of CH2BrCH2Br, CH 2BrCH2Cl, and CH2BrCD2Cl: Identification of the Cl-Br interchange reaction
Friederich, Laura,Duncan, Juliana R.,Heard, George L.,Setser,Holmes, Bert E.
experimental part, p. 4138 - 4147 (2010/09/04)
The recombination reactions of CH2Br and CH2Cl radicals have been used to generate vibrationally excited CH 2BrCH2Br and CH2BrCH2Cl molecules with 91 kcal mol-1 of energy in a room-temperature bath gas. The experimental unimolecular rate constants for elimination of HBr and HCl were compared to calculated statistical rate constants to assign threshold energies of 58 kcal mol-1 for HBr elimination from C2H 4Br2 and 58 and 60 kcal mol-1, respectively, for HBr and HCl elimination from C2H4BrCl. The Br-Cl interchange reaction was demonstrated and characterized by studying the CH 2BrCD2Cl system generated by the recombination of CH 2Br and CD2Cl radicals. The interchange reaction was identified from the elimination of HBr and DCl from CH2ClCD 2Br. The interchange reaction rate is much faster than the rates of either DBr or HCl elimination from CH2BrCD2Cl, and a threshold energy of ?43 kcal mol-1 was assigned to the interchange reaction. The statistical rate constants were calculated from models of the transition states that were obtained from density functional theory using the B3PW91 method with the 6-31G(d′,p′) basis set. The model for HBr elimination was tested versus published thermal and chemical activation data for C2H5Br. A comparison of Br-Cl interchange with the Cl-F and Br-F interchange reactions in 1,2-haloalkanes is presented.
Mechanism of the reaction of vinyl chloride with (α-diimine)PdMe + species
Kilyanek, Stefan M.,Stoebenau, Edward J.,Vinayavekhin, Nawaporn,Jordan, Richard F.
experimental part, p. 1750 - 1760 (2010/06/13)
The reaction of vinyl chloride (VC) with (α-diimine)PdMe+ species yields (α-diimine)PdCl(propene)+. Isotope labeling experiments using the deuterium-labeled vinyl chlorides 1-VC-d1 and Z-VC-d1 combined with DFT
