499189-68-3Relevant academic research and scientific papers
Iron-catalyzed C-C bond cleavage and C-N bond formation
Li, Wenjuan,Zheng, Xiaojian,Li, Zhiping
, p. 181 - 190 (2013/03/13)
A novel approach for C-N bond formation was developed by iron-catalyzed C-C bond cleavage. Anilines and sulfonamides reacted smoothly with 2-substituted 1,3-diphenylpropane-1,3-diones to afford N-alkylation products, in which the 1,3-dicarbonyl group acts as a leaving group in the presence of an iron catalyst. The reversible C-C bond cleavage plays a driving force to give the thermodynamically stable products. The method is complementary to the previous methods for C-N bond formation. Copyright
