499798-17-3Relevant academic research and scientific papers
gem-Silylborylation of an sp carbon: Novel synthesis of 1-boryl-1-silylallenes
Shimizu, Masaki,Kurahashi, Takuya,Kitagawa, Hirotaka,Hiyama, Tamejiro
, p. 225 - 227 (2007/10/03)
(Matrix presented) Novel synthesis of 1-boryl-1-silylallenes involving gem-silylborylation of 3-chloro- or 3-alkoxyalkyn-1-yllithiums with (dimethylphenylsilyl)-(pinacolato)borane has been established. The reaction proceeds via 1,2-migration of the silyl
