500004-47-7Relevant articles and documents
The 1,4-addition of organometallic reagents to enoates derived from pinanediol
Pinheiro, Sergio,Pedraza, Sergio F.,Peralta, Monica A.,Teixeira, Rafael C.,De Farias, Florence M. C.,Ferreira, Vitor F.,Costa, Paulo R. R.
, p. 2513 - 2517 (2002)
The complex-induced, proximity effect-promoted 1,4-addition of RCu·BF3 and R2CuLi to enoates derived from (-)-pinanediol leads to adducts with the opposite sense of chirality (up to 98% d.e.).