500295-52-3 Usage
Uses
Used in Photocatalysis:
Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III) is used as a photocatalyst for facilitating a variety of chemical transformations using visible light. One of its notable applications is the defluorination of arenes, which is an important reaction in the synthesis of various organic compounds and materials. Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III)'s ability to absorb visible light and generate reactive intermediates makes it an efficient catalyst for this process.
Used in Organic Synthesis:
In the field of organic synthesis, Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III) can be employed as a catalyst for various reactions, such as C-H activation, cross-coupling, and cyclization. Its unique electronic and steric properties enable it to promote selective and efficient transformations, making it a valuable tool for the synthesis of complex organic molecules.
Used in Materials Science:
The photophysical properties of Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III) make it a potential candidate for applications in the field of materials science. It can be used in the development of light-emitting diodes (LED), photovoltaic cells, and other optoelectronic devices, where its ability to absorb and emit light can be harnessed for energy conversion and light emission.
Used in Pharmaceutical Applications:
Although not explicitly mentioned in the provided materials, the unique structure and properties of Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III) may also make it a candidate for pharmaceutical applications. Its coordination chemistry and potential interactions with biological targets could be explored for the development of new drugs or drug delivery systems.
Check Digit Verification of cas no
The CAS Registry Mumber 500295-52-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 5,0,0,2,9 and 5 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 500295-52:
(8*5)+(7*0)+(6*0)+(5*2)+(4*9)+(3*5)+(2*5)+(1*2)=113
113 % 10 = 3
So 500295-52-3 is a valid CAS Registry Number.
500295-52-3Relevant academic research and scientific papers
METHOD FOR THE SYNTHESIS AND ISOLATION OF FACIAL-TRIS-HOMOLEPTIC PHENYLPYRIDINATO IRIDIUM (III) PHOTOCATALYSTS
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Paragraph 0161-0164; 0165, (2018/09/28)
Methods of synthesizing and isolating facial-tris-homoleptic phenylpyridinato iridium (III) photocatalysts are disclosed. Also disclosed are methods of recovering excess 2- phenylpyridine ligands from said syntheses.
Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis
Singh, Anuradha,Teegardin, Kip,Kelly, Megan,Prasad, Kariate S.,Krishnan, Sadagopan,Weaver, Jimmie D.
, p. 51 - 59 (2015/02/19)
Herein we describe an improved synthesis for homoleptic iridium(III) 2-phenylpyridine based photocatalysts that allows rapid access to these compounds in good to high yields which have recently become a vital component within the field of catalysis. In addition, we synthesized a number of heteroleptic iridium(III) 2-phenylpyridine photocatalysts and report their photophysical and electrochemical properties. The emission energies span the range of 473-560 nm and reduction potentials from -2.27 V to -1.23 V and oxidation potentials ranging from 1.81 V to 0.69 V. Additionally, we provide the calculated excited state properties and comment on the role of these properties in designing catalytic cycles.
