500297-38-1

Basic information

• Product Name: 3,6,9,12-Tetraoxatetradecane, 1,14-bis[2,6-bis(bromomethyl)-4-methylphenoxy]-
• CAS NO: 500297-38-1
• Molecular Formula: C28H38Br4O6
• Molecular Weight: 790.222
• Mol File: 500297-38-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,6,9,12-Tetraoxatetradecane, 1,14-bis[2,6-bis(bromomethyl)-4-methylphenoxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6,9,12-Tetraoxatetradecane, 1,14-bis[2,6-bis(bromomethyl)-4-methylphenoxy]-(500297-38-1)
• EPA Substance Registry System: 3,6,9,12-Tetraoxatetradecane, 1,14-bis[2,6-bis(bromomethyl)-4-methylphenoxy]-(500297-38-1)

Safety Data

• Hazardous Substances Data: 500297-38-1(Hazardous Substances Data)

Upstream product

• 57602-02-5 1,14-dibromo-3,6,9,12-tetraoxatetradecane 
• 91-04-3 2,6-bis(hydroxymethyl)-4-methylphenol 
• 500297-36-9 (2-{2-[2-(2-{2-[2-(2,6-bis-hydroxymethyl-4-methyl-phenoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-3-hydroxymethyl-5-methyl-phenyl)-methanol 

Relevant articles and documents

Complexation behavior and crystal structure of a dithia[16.3.3](1,2,6)cyclophane: A novel one-dimensional coordination polymer with perchlorate anions as linkers

The synthesis of 20,28-dimethyl-24,33-dithia-1,4,7,10,13,16-hexaoxa[16.3.3](1,2,6)cyclophane 3 was achieved by cesium carbonate-assisted high dilution cyclization. Cyclophane 3 exhibited strong complexation towards all alkali metal ions. The change in chemical shift for the bridge methylene protons upon addition of alkali metal ions correlated to log Ka. The crystal structure of cyclophane 3 as well as its sodium and potassium complexes was studied. Cyclophane 3 formed a novel one-dimensional coordination polymer with potassium perchlorate using anions as the linkers, while the complex of 3 with sodium perchlorate had a dimeric structure.