500362-90-3Relevant academic research and scientific papers
Reaction of difluorocarbene with 2H-azirines: Generation and transformations of strained azomethine ylides - Aziriniodifluoromethanides
Khlebnikov,Novikov,Amer
, p. 1092 - 1101 (2007/10/03)
The reaction of difluorocarbene with azirines affords a new type of azomethine ylides, viz., strained aziriniodifluoromethanides. 1,3-Dipolar cycloadditions of ylides derived from 2-unsubstituted 3-arylazirines to dimethyl acetylenedicarboxylate and aldeh
Generation and cycloadditions of azirinium difluoromethanides - Strained azomethine ylides
Khlebnikov, Alexander F.,Novikov, Mikhail S.,Amer, Amer A.
, p. 8523 - 8525 (2007/10/03)
The reaction of 3-aryl-2H-azirines with difluorocarbene involves the formation of azirinium difluoromethanides - the first strained azomethine ylides which undergo 1,3-dipolar cycloaddition with dimethyl acetylenedicarboxylate, giving rise to fluorinated
