500899-32-1Relevant academic research and scientific papers
Stereo- And Regioselective cis-Hydrophosphorylation of 1,3-Enynes Enabled by the Visible-Light Irradiation of NiCl2(PPh3)2
Hou, Hong,Zhou, Bing,Wang, Jiawei,Zhao, Dengyang,Sun, Duhao,Chen, Xiaoyun,Han, Ying,Yan, Chaoguo,Shi, Yaocheng,Zhu, Shaoqun
supporting information, p. 2981 - 2987 (2021/05/05)
Described herein is a stereo- and regioselective cis-hydrophosphorylation reaction of the internal alkyne of 1,3-enynes that accesses various 1,3-dienes in good isolated yields. The visible-light irradiation of NiCl2(PPh3)2 allows the generation of highly reactive nickel(II)-phosphorus species that subsequently migrate into the internal alkyne of the 1,3-enynes and protonate the resulting vinyl nickel species, leading to various phosphinoyl 1,3-butadienes under mild reaction conditions.
Preparation of conjugated enynes and arylacetylenic compounds from arylalkynols using alumina in dry media
Pourjavadi, Ali,Bagheri Marandi, Gholam
, p. 552 - 555 (2007/10/03)
Arylalkynols were converted into both conjugated enynes and arylacetylenic compounds using p-TsCl/Al2O3 and KOH/Al2O3 respectively in classical heating or microwave irradiation methods in good yields.
Selective synthesis of conjugated enynes from α-arylalkynols using LiCl-Acidic Al2O3 under solvent-free conditions
Pourjavadi, Ali,Marandi, Gholam Bagheri
, p. 378 - 380 (2007/10/03)
α-Arylalkynols were converted into conjugated enynes (in a selective manner under solvent-free conditions) using the LiCl-acidic Al2O3 couple as catalyst and support.
