500991-84-4Relevant academic research and scientific papers
SYNTHESIS OF PERYLENE-PORPHYRIN BUILDING BLOCKS AND POLYMERS THEREOF FOR THE PRODUCTION OF LIGHT-HARVESTING ARRAYS
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Page 50-51, 85, (2008/06/13)
The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula (I): wherein m is at least 1; X1 is a charge separation group, and X2 through Xm+1 are chromophores. At least one of X2 through Xm+1 has at least one perylene group coupled thereto.
Synthesis of perylene - Porphyrin building blocks and rod-like oligomers for light-harvesting applications
Loewe, Robert S.,Tomizaki, Kin-Ya,Youngblood, W. Justin,Bo, Zhishan,Lindsey, Jonathan S.
, p. 3438 - 3451 (2007/10/03)
We present the synthesis of four perylene - porphyrin building blocks for use in Glaser, Sonogashira, or Suzuki polymerizations. The building blocks bear synthetic handles (4-ethynylphenyl, 4-iodophenyl, bromo) at the trans (5,15) meso-positions of a zinc
