501373-19-9

Basic information

• Product Name: (E)-(2R,4S,5R)-3-(5-hydroxy-2-phenyl-[1,3]dioxane-4-yl)-acrylic acid ethyl ester
• Synonyms: (E)-(2R,4S,5R)-3-(5-hydroxy-2-phenyl-[1,3]dioxane-4-yl)-acrylic acid ethyl ester
• CAS NO: 501373-19-9
• Molecular Weight: 278.305
• Mol File: 501373-19-9.mol

Chemical Properties

• CAS DataBase Reference: (E)-(2R,4S,5R)-3-(5-hydroxy-2-phenyl-[1,3]dioxane-4-yl)-acrylic acid ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(2R,4S,5R)-3-(5-hydroxy-2-phenyl-[1,3]dioxane-4-yl)-acrylic acid ethyl ester(501373-19-9)
• EPA Substance Registry System: (E)-(2R,4S,5R)-3-(5-hydroxy-2-phenyl-[1,3]dioxane-4-yl)-acrylic acid ethyl ester(501373-19-9)

Safety Data

• Hazardous Substances Data: 501373-19-9(Hazardous Substances Data)

Upstream product

• 86302-43-4 (tert-Butoxycarbonylmethylene)triphenylphosphorane 
• 81577-69-7 [2R,4R,5R]-5-hydroxy-2-phenyl-[1,3]dioxane-4-carbaldehyde 
• 3006-41-5 4,6-O-benzylidene-D-glucose 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 501373-23-5 (E)-3-[5-(R)-(imidazole-1-carbonothioyloxy)-2-(R)-phenyl-[1,3]dioxan-4-(S)-yl]acrylic acid ethyl ester 

Relevant articles and documents

Stereochemical control in radical cyclization routes to N-glycosides: Role of protecting groups and of the configuration (E versus Z) of the acceptors

The first radical intermediate in the thiourethane-mediated deoxygenation of an alcohol (Barton-McCombie reaction) can participate in an exo-hex-5-enyl or exo-hept-6-enyl type radical cyclization when a suitable radical acceptor (e.g. α,β-unsaturated este

A new reaction manifold for the Barton radical intermediates: Synthesis of N-heterocyclic furanosides and pyranosides via the formation of the C1-C2 bond

The first radical intermediate in the thiourethane-mediated deoxygenation of an alcohol (Barton-McCombie reaction) can participate in an exo-hex-5-enyl- or exo-hept-6-enyl-type radical cyclization when a suitable radical acceptor (e.g., α,β-unsaturated es