501428-25-7Relevant academic research and scientific papers
Synthesis of Flavanones via Palladium(II)-Catalyzed One-Pot β-Arylation of Chromanones with Arylboronic Acids
Cho, Yang Yil,Jang, Hyu Jeong,Kim, Dong Hwan,Kim, Nam Yong,Kim, Nam-Jung,Kim, Young Min,Lee, Soo Jin,Lee, Yong Sup,Park, Boyoung Y.,Son, Seung Hwan,Yoo, Hyung-Seok
supporting information, p. 10012 - 10023 (2019/08/30)
A total of 47 flavanones were expediently synthesized via one-pot β-arylation of chromanones, a class of simple ketones possessing chemically unactivated β sites, with arylboronic acids via tandem palladium(II) catalysis. This reaction provides a novel route to various flavanones, including natural products such as naringenin trimethyl ether, in yields up to 92percent.
Studies towards the stereoselective α-hydroxylation of flavanones. Biosynthetic significance
Border, Zola-Michele,Marais, Charlene,Bezuidenhoudt, Barend C. B.,Steenkamp, Jacobus A.
, p. 122 - 130 (2008/04/11)
The enolates of various propiophenones, chromanones, and also analogues of naturally occurring flavanones were stereoselectively hydroxylated at the ?-position, by employing commercially available enantiopure oxaziridines, to afford the desired ?-hydroxylated target molecules in good to exceptional stereoselectivities and in moderate to good chemical yields. A mechanistic rationale is presented to account for the stereoselectivities achieved. These in vitro results were tentatively related to the stereoselective biosynthesis of enantio-enriched dihydroflavonols while questions were raised about the authenticity of certain natural compounds. CSIRO 2008.
Cesium fluoride-Celite: A solid base for efficient syntheses of aromatic esters and ethers
Shah, Syed Tasadaque Ali,Khan, Khalid Mohammed,Hussain, Hidayat,Anwar, Muhammad Usman,Fecker, Miriam,Voelter, Wolfgang
, p. 6652 - 6656 (2007/10/03)
Coupling reactions of a number of aromatic and heteroaromatic phenols with alkyl, acyl or benzoyl halides in acetonitrile with cesium fluoride-Celite are described, demonstrating that this reagent provides an efficient, convenient and practical method for the syntheses of aromatic esters and ethers.
An efficient approach towards syntheses of ethers and esters using CsF-Celite as a solid base
Shah, Syed Tasadaque A,Khan, Khalid M,Heinrich, Angelica M,Choudhary, M.Iqbal,Voelter
, p. 8603 - 8606 (2007/10/03)
The coupling reactions of a number of alcohols and phenols with alkyl, acyl or benzoyl halides in acetonitrile with cesium fluoride-Celite are described. It has been found that CsF-Celite combinations provide an efficient, convenient and practical method for syntheses of both, ethers and esters.
