501649-30-5Relevant academic research and scientific papers
A general method for meta and para functionalization of arenes using TMP2Mg·2 LiCl
Rohbogner, Christoph J.,Clososki, Giuliano C.,Knochel, Paul
, p. 1503 - 1507 (2008/12/23)
(Chemical Equation Presented) Getting directions: The (Me 2N)2P(O)O substituent serves as an effective directing-metalation group in the magnesiation of substituted arenes with TMP2Mg·2 LiCl (see scheme). This reaction can
Direct magnesiation of polyfunctionalized arenes and heteroarenes using (tmp)2Mg·2 LiCl
Clososki, Giuliano C.,Rohbogner, Christoph J.,Knochel, Paul
, p. 7681 - 7684 (2008/09/18)
(Chemical Equation Presented) Outstripping lithium bases: A wide range of polyfunctional aryl and heteroaryl magnesium reagents were efficiently prepared in THF by direct magnesiation with (tmp)2Mg·2 LiCl, an exceptionally active base. These co
