502613-91-4

Upstream product

• 502614-14-4 (-)-(2R,3S)-4-(benzyloxy)-4-methyl-3-[(methylsulfanyl)methoxy]pentane-1,2-diol 
• 139629-93-9 (2R,3R)-1,2-O-isopropylidene-4-methyl-4-pentene-1,2,3-triol 
• 83657-30-1 (+)-(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-1-hydroxypropan-2-one 
• 502614-15-5 (-)-(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methylpropane-1,2-diol 
• 502614-16-6 (+)-(1S)-1-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-methyl-1-[(methylsulfanyl)methoxy]propan-2-ol 
• 502614-13-3 (+)-(4R)-4-{(1S)-2-(benzyloxy)-2-methyl-1-[(methylsulfanyl)methoxy]propyl}-2,2-dimethyl-1,3-dioxolane 
• 106513-41-1 1-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propenone 

Downstream Products

• 671792-46-4 (2S,3S)-4-Benzyloxy-1-iodo-4-methyl-3-methylsulfanylmethoxy-pentan-2-ol 
• 671792-39-5 2-[2-amino-5-(3-methyl-but-2-enyl)-phenyl]-1-[8-hydroxymethyl-6a,7-dimethyl-3-(1-methyl-1-triethylsilanyloxy-ethyl)-2-triethylsilanyloxy-2,3,4a,5,6,6a,7,8,9,10-decahydro-1H-benzo[f]chromen-7-yl]-ethanone 
• 671792-49-7 Benzoic acid (1R,2S)-3-benzyloxy-1-[(1R,3aR,9aS,9bS)-7-(dimethyl-hydrazono)-1-methoxy-9a,9b-dimethyl-1,3,3a,4,5,7,8,9,9a,9b-decahydro-naphtho[1,2-c]furan-6-ylmethyl]-3-methyl-2-methylsulfanylmethoxy-butyl ester 
• 671792-30-6 (+)-(1R,2S)-3-(benzyloxy)-1-{[(1R,9aS,9bS)-1,3,3a,4,5,7,8,9,9a,9b-decahydro-1-methoxy-9a,9b-dimethyl-7-oxonaphtho[1,2-c]furan-6-yl]methyl}-3-methyl-2-[(methylsulfanyl)methoxy]butyl benzenecarboxylate 
• 671792-47-5 Benzoic acid (1R,2S)-3-benzyloxy-1-[(S)-2-(dimethyl-hydrazono)-4a-methyl-2,3,4,4a,5,6,7,8-octahydro-naphthalen-1-ylmethyl]-3-methyl-2-methylsulfanylmethoxy-butyl ester 
• 502614-18-8 Benzoic acid (2R,3S,8S,13R,14S)-3-(1-benzyloxy-1-methyl-ethyl)-8,14-dimethyl-15-oxo-1,2,3,6,8,12,13,14,15,17-decahydro-7H-4,16-dioxa-cyclopenta[a]phenanthren-2-yl ester 
• 671792-34-0 (+)-(2S,3R,9aS,9bS,11aS)-3,4,5,6,6a,7,9,9a,9b,10,11,11a-dodecahydro-2-(1-hydroxy-1-methylethyl)-9a,9b-dimethyl-9-oxo-2H-[2]benzofuro[5,4-f][1]benzopyran-3-yl benzenecarboxylate 
• 671792-37-3 (+)-(2R,4bS,9aS,9bR,11aS)-2-[1-(benzyloxy)-1-methylethyl]-5,6,6a,7,9,9a,9b,10,11,11a-decahydro-4b-(hydroperoxy)-9a,9b-dimethyl-2H-[2]benzofuro[5,4-f][1]benzopyran-3,9(4bH)-dione 
• 671792-36-2 (+)-(2S,3R,9aS,9bS,11aS)-2-[1-(benzyloxy)-1-methylethyl]-3,4,5,6,6a,7,9,9a,9b,10,11,11a-dodecahydro-9a,9b-dimethyl-2H-[2]benzofuro[5,4-f][1]benzopyran-9-one 
• 502614-05-3 (-)-{(2R,3S,4aS,6aR,7S,10aS,11aR)-3-[1-(benzyloxy)-1-methylethyl]-2,3,4a,5,6,6a,7,8,9,10-decahydro-6a,7-dimethyl-7-[5-(3-methylbut-2-enyl)-1H-indol-2-yl]-2-[(triethylsilyl)oxy]-1H-benzo[f]oxireno[2,3-e][1]benzopyran-8-yl}methyl metanesulfonate 
• 502614-06-4 (-)-(2S,3R,4aR,5aS,13bS,13cR,15aS)-2-[1-(benzyloxy)-1-methylethyl]-3,4,5,6,7,7a,8,13,13b,13c,14,15,15a-dodecahydro-13b,13c-dimethyl-10-(3-methylbut-2-enyl)-3-[(triethylsilyl)oxy]-2H-oxireno[2'',3'':4a',5'][1]benzopyrano[5'6':6,7]indeno[1,2-b]indole 
• 502614-04-2 (-)-{(2R,3S,4aS,6aR,7S,10aS,11aR)-3-[(1-(benzyloxy)-1-methylethyl]-2,3,4a,5,6,6a,7,8,9,10-decahydro-6a,7-dimethyl-7-[5-3-methylbut-2-enyl)-1H-indol-2-yl]-2-[(triethylsilyl)oxy]-1H-benzo[f]oxireno[2,3-e][1]benzopyran-8-yl}methanol 
• 502614-07-5 (-)-(2S,3R,4aR,5aS,13bS,13cR,15aS)-2-[1-(benzyloxy)-1-methylethyl]-3,4,5,6,7,7a,8,13,13b,13c,14,15,15a-dodecahydro-13b,13c-dimethyl-10-(3-methylbut-2-enyl)-2H-oxireno[2'',3'':4a',5'][1]benzopyrano[5'6':6,7]indeno[1,2-b]indol-3-ol 
• 502614-08-6 (+)-(2R,4bS,12bS,12cR,14aS)-2-[1-(benzyloxy)-1-methylethyl]-5,6,6a,7,12,12b,12c,13,14,14a-decahydro-4b-hydroxy-12b,12c-dimethyl-9-(3-methylbut-2-enyl)-2H-[1]benzopyrano[5'6':6,7]indeno[1,2-b]indol-3(4bH)-one 

Relevant academic research and scientific papers

Total synthesis of (-)-21-isopentenylpaxilline.

[structure: see text] The total synthesis of (-)-21-isopentenylpaxilline (1) has been achieved. Key elements of the synthesis include the stereocontrolled construction of the advanced eastern hemisphere (-)-5, a highly efficient union of the eastern and w

Indole-Diterpene Synthetic Studies: Total Synthesis of (-)-21-Isopentenylpaxilline

An efficient, stereocontrolled total synthesis of the complex indole-diterpene alkaloid (-)-21-isopentenylpaxilline (1) has been achieved. Key elements of the synthesis include the stereocontrolled construction of the advanced eastern hemisphere (-)-68, i